Next, let's draw proline; its "R group" is a ring structure that includes the amino group and the alpha carbon, which is different from the other amino acids.
- Indicate that proline is also denoted as Pro, or P.
- Draw our general amino acid stick structure but omit one of the hydrogen atoms of the amino group.
- Now, use a pentagon to connect the central carbon to the nitrogen atom of the amino group.
- This is called an imino ring, and it gives proline its unique features.
- Proline is unfavorable (like glycine) but for the opposite reason: its bulky imino ring constrains its flexibility.